Coffee and aspirin best hangover cure
If you really want help overcoming a hangover, drink a cup of coffee with an aspirin. Scientists have found the caffeine in coffee and the anti-inflammatory ingredients of aspirin and other painkillers reacted against the chemical compounds of ethanol, or pure alcohol. Ethanol brings on headaches thanks to a chemical acetate it can produce.
http://www.telegraph.co.uk/health/healthnews/8264521/Coffee-and-an-aspirin-best-hangover-cure-after-all.html

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